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Cross-linking strategy for solar cells

Due to the limited interface contact and weak interfacial interaction, planar heterojunction perovskite solar cells (PSCs) have space for further improvement. Herein, a …

Are cross-linking strategies effective in achieving efficient and stable PSCs?

Finally, future perspectives and directions for cross-linking strategies are provided, which are expected to gather further research momentum in exploiting more efficient and durable cross-linking approaches to realize efficient, highly stable PSCs.

Why is in situ cross-linking important?

However, the instability of PSCs severely impedes their commercialization. Recently, in situ cross-linking strategy has been proposed to mitigate stability issues of PSCs, enabling highly efficient and stable PSCs. Here, the critical factors that lead to the degradation of PSCs are first outlined.

Does in situ cross-linking strategy exist in PSCs and other optoelectronic devices?

Finally, the current challenges and further development trends of in situ cross-linking strategy in PSCs and extension to other optoelectronic devices are prospected. The authors declare no conflict of interest.

Why are cross-linkable organic molecules important?

Recently, the cross-linking strategies involving cross-linkable organic molecules have come to the fore due to their great potential in synchronously enhancing the intrinsic, processing, thermal, and mechanical stabilities of perovskites.

How to improve the stability of solar cell devices?

Defective grain boundaries of polycrystalline perovskite films are one of the major causes of the instability of the solar cell devices. Here Han et al. choose a polymer with proper molecular structure to crosslink the perovskite grains to greatly improve the device stability.

Does in situ cross-linking polymerization improve crystal growth of perovskite films?

Comparatively speaking, in situ cross-linking polymerization shows more obvious superiority in the nucleation and crystal growth of perovskite films. However, no literature systematically reports the research progress and mechanism of the in situ polymerization reaction.

Universal Strategy with Structural and Chemical Crosslinking …

Due to the limited interface contact and weak interfacial interaction, planar heterojunction perovskite solar cells (PSCs) have space for further improvement. Herein, a …

Importance of Functional Groups in Cross-Linking Methoxysilane ...

@article{Xie2019ImportanceOF, title={Importance of Functional Groups in Cross-Linking Methoxysilane Additives for High-Efficiency and Stable Perovskite Solar Cells}, author={Lin Xie and Jiangzhao Chen and Parth Vashishtha and Xing Zhao and Gwang Su Shin and Subodh Gautam Mhaisalkar and Nam‐Gyu Park}, journal={ACS Energy Letters}, year={2019 ...

Mechanically and operationally stable flexible inverted perovskite ...

The cross-linked polymer adhered to the GBs facilitated the stability by strengthening the interface binding between the GBs and encapsulating the grains to suppress …

In-situ cross-linking strategy for efficient and …

Here we demonstrate an in-situ cross-linking strategy for operationally stable inverted MAPbI 3 PSCs through the incorporation of a …

In Situ Cross‐Linking Strategy to Enable Highly Stable …

Recently, in situ cross-linking strategy has been proposed to mitigate stability issues of PSCs, enabling highly efficient and stable PSCs. Here, the critical factors that lead to the degradation of PSCs are first outlined. Then, …

Crosslinker-stabilized quasi-two-dimensional perovskite for solar ...

Upscaling perovskite solar cells to the module level while ensuring long-term stability is crucial for their commercialization. Here, we report a bottom-up crosslinking strategy utilizing 4-(aminomethyl)benzoic acid as a dual-anchor linker integrated into quasi-two-dimensional (2D) perovskite to reduce the weak van der Waals gap between individual 3D …

Triple Cross‐Linking Engineering Strategies for Efficient and …

Inverted flexible perovskite solar cells (fPSCs) are promising for commercialization due to their low cost, lightweight, and excellent stability. However, enhancing fPSCs'' power conversion efficiency and stability remains challenging. Here, an unprecedented triple cross-linking engineering strategy is innovatively exhibit for ...

Cross-linking strategies for efficient and highly stable …

Recently, the cross-linking strategies involving cross-linkable organic molecules have come to the fore due to their great potential in synchronously enhancing the intrinsic, processing, thermal, and mechanical …

Simultaneously Enhancing Efficiency and Stability …

Here, a one-step solution-processing strategy is demonstrated for preparing efficient and stable inverted methylammonium lead iodide (MAPbI 3) perovskite solar cells (PSCs) by incorporating a series of organic molecule …

Triple Cross‐Linking Engineering Strategies for Efficient and Stable ...

Inverted flexible perovskite solar cells (fPSCs) are promising for commercialization due to their low cost, lightweight, and excellent stability. However, …

Cross-linking polymerization boosts the performance …

Perovskite polycrystalline films with massive grain boundaries (GBs) lead to high defect densities as well as poor environmental stability. Polymer additives provide an effective insight to solve these problems. …

Supporting Information

Star-Polymer Multidentate-Cross-Linking Strategy for Superior Operational Stability of Inverted Perovskite Solar Cells at High Efficiency Qi Cao, a Jiabao Yang, a Tong Wang, a Yuke Li, b Xingyu Pu, a Junsong Zhao, a Yixin Zhang, a Hui Zhou, a Xiaoqiang Li, a and Xuanhua Li a * a. State Key Laboratory of Solidification Processing, Center for ...

Cross-linkable molecule in spatial dimension boosting water …

PETA-G can crosslink a framework in spatial dimension with high crosslinking degree on perovskite film. The crosslinking framework improves the water-resistance ability of …

Cross-linking polymerization boosts the performance of perovskite solar …

Perovskite polycrystalline films with massive grain boundaries (GBs) lead to high defect densities as well as poor environmental stability. Polymer additives provide an effective insight to solve these problems. However, certain polymers originating from ex situ polymerization have poor solubility and adversely affect perovskite nucleation.

Universal Strategy with Structural and Chemical Crosslinking …

Perovskite solar cells (PSCs) have been developed rapidly due to the evolution of perovskite films and charge transport layers. [ 1, 2 ] Generally, there are lots of undercoordinated halide ions and undercoordinated Pb 2+ ions on the surface of perovskite films, [ 3 ] which lead to deep energy level traps and charge carrier recombination centers and deteriorate the …

In Situ Cross‐Linking Strategy to Enable Highly Stable Perovskite Solar …

Recently, in situ cross-linking strategy has been proposed to mitigate stability issues of PSCs, enabling highly efficient and stable PSCs. Here, the critical factors that lead to the degradation of PSCs are first outlined. Then, a comprehensive review of in situ cross-linking strategy in perovskite to enhance the moisture, thermal ...

Star-polymer multidentate-cross-linking strategy for …

Here, we propose a multidentate-cross-linking strategy, which uses multi-branched and adequate chemical anchor sites in three-dimensional star-polymer to directly chelate perovskite materials in multiple directions, thereby …

Mechanically and operationally stable flexible inverted perovskite ...

The cross-linked polymer adhered to the GBs facilitated the stability by strengthening the interface binding between the GBs and encapsulating the grains to suppress ion migration and water/oxygen permeation. Our investigation provides a promising strategy for producing efficient and stable FPSCs.

In-situ cross-linking strategy for efficient and operationally stable ...

Long-term operational stability is the foremost issue delaying the commercialization of perovskite solar cells (PSCs). Here we demonstrate an in-situ cross-linking strategy for operationally stable inverted MAPbI 3 PSCs through the incorporation of a cross-linkable organic small molecule additive trimethylolpropane triacrylate (TMTA) into perovskite …

In-situ cross-linking strategy for efficient and operationally stable ...

ARTICLE In-situ cross-linking strategy for efficient and operationally stable methylammoniun lead iodide solar cells Xiaodong Li 1, Wenxiao Zhang1,2, Ying-Chiao Wang 1, Wenjun Zhang1,2, Hai-Qiao ...

Star-polymer multidentate-cross-linking strategy for superior ...

@article{Cao2021StarpolymerMS, title={Star-polymer multidentate-cross-linking strategy for superior operational stability of inverted perovskite solar cells at high efficiency}, author={Qipeng Cao and Jiabao Yang and Tong Wang and Yuke Li and Xingyu Pu and Junsong Zhao and Yixin Zhang and Hui Zhou and Xiaoqiang Li and Xuanhua Li}, journal ...

Star-polymer multidentate-cross-linking strategy for superior ...

Here, we propose a multidentate-cross-linking strategy, which uses multi-branched and adequate chemical anchor sites in three-dimensional star-polymer to directly chelate perovskite materials in multiple directions, thereby regulating the morphology of perovskite, passivating defects at surface/GBs, inhibiting the non-radiative recombination ...

Cross-linking strategies for efficient and highly stable perovskite ...

Recently, the cross-linking strategies involving cross-linkable organic molecules have come to the fore due to their great potential in synchronously enhancing the intrinsic, processing, thermal, and mechanical stabilities of perovskites. Hence, in this review, the recent advances in cross-linking methods utilized in PSCs are ...

In-situ cross-linking strategy for efficient and operationally stable ...

Here we demonstrate an in-situ cross-linking strategy for operationally stable inverted MAPbI 3 PSCs through the incorporation of a cross-linkable organic small molecule additive...

Cross-linkable molecule in spatial dimension boosting water-stable …

PETA-G can crosslink a framework in spatial dimension with high crosslinking degree on perovskite film. The crosslinking framework improves the water-resistance ability of perovskite film even immersing into water. PETA-G can repair the perovskite film morphology and electronic defects.

Perovskite-polymer composite cross-linker approach for highly …

Here, we introduce an inter-grain cross-linking strategy, induced by a macromolecular intermediate phase with a polymeric Lewis base, for simple fabrication of highly efficient and stable...

Universal Strategy with Structural and Chemical Crosslinking …

Due to the limited interface contact and weak interfacial interaction, planar heterojunction perovskite solar cells (PSCs) have space for further improvement. Herein, a structural and chemical crosslinking interface is proposed and constructed by introducing an extra layer, which blends tin dioxide (SnO 2 ) nanoparticles with ...

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