Thin film solar cells are favorable because of their minimum material usage and rising efficiencies. The three major thin film solar cell technologies include amorphous silicon (α-Si), copper indium gallium selenide (CIGS), and cadmium telluride (CdTe).
In 1981, Mickelsen and Chen demonstrated a 9.4% efficient thin-film CuInSe2/CdS solar cell. The efficiency improvement was due to the difference in the method of evaporating the two selenide layers. The films were deposited with fixed In and Se deposition rates, and the Cu rate was adjusted to achieve the desired composition and resistivity.
Typically, any thin film solar cells suffer from a huge reduction in light absorption within absorber layers (semiconductors), and that can cause efficiency drop due to inherent surface reflection. To achieve higher efficiency, some boosting techniques have been developed for better light absorption.
As an alternative to single crystal silicon photovoltaics, thin film solar cells have been extensively explored for miniaturized cost-effective photovoltaic systems. Though the fight to gain efficiency has been severely engaged over the years, the battle is not yet over.
In this work, we fabricated Ag-CZTSSe thin-film solar cells using eco-friendly ZTO as a buffer layer deposited by ALD method with optimal stoichiometry and film thickness, which significantly improved the efficiency of kesterite solar cells.
A CTO/ZTO/CdS/CdTe polycrystalline thin-film solar cell with an NREL-confirmed total-area efficiency of 16.5% ( Voc = 845.0 mV, Jsc = 25.88 mA/cm 2, FF = 75.51%, and area = 1.032 cm 2) was achieved, which is the highest efficiency ever reported for CdS/CdTe solar cells.
High efficiency thin-film amorphous silicon solar cells
Enhancing light absorption within thin film amorphous silicon (a-Si) solar cells should lead to higher efficiency. This improvement is typically done using various light trapping techniques such as utilizing textured back reflectors for pronounced light scattering within the cell thus achieving higher absorption. It is believed that embedding ...
High-Efficiency Solution-Processed Cu2ZnSn(S,Se)4 Thin-Film Solar Cells ...
A new solution-based method to fabricate Cu 2 ZnSn (S,Se) 4 (CZTSSe) thin films is presented. Binary and ternary chalcogenide nanoparticles were synthesized and used as precursors to form CZTSSe thin films. The composition of the CZTSSe films can be easily controlled by adjusting the ratio of the nanoparticles used.
Cadmium‐Free Kesterite Thin‐Film Solar Cells with …
In this work, we fabricated Ag-CZTSSe thin-film solar cells using eco-friendly ZTO as a buffer layer deposited by ALD method with optimal stoichiometry and film thickness, which significantly improved the efficiency of kesterite solar cells. …
A Comprehensive Survey of Silicon Thin-film Solar …
CdTe thin-film solar cells have high efficiency. The compound is stable and has a direct bandgap, similar to CIGS. Thin CdTe films have the potential to produce high-efficiency cells if bulk and surface recombination are …
Non-toxic materials for high efficiency thin-film solar cells: …
Thin-film solar cells based on Cu 2 ZnSn (S,Se) 4 (CZTSSe) are a promising technology for developing high-efficiency photo voltaic cells. These cells have excellent optical properties, a high absorption coefficient of over 10 4 cm −1, and are made from abundant, non-toxic materials. The bandgap of CZTSSe can be adjusted between 1.0 to 1.5 eV.
A review of thin film solar cell technologies and challenges
Thin film solar cells are favorable because of their minimum material usage …
High efficiency solution-processed thin-film Cu (In,Ga) (Se,S)
The polycrystalline chalcopyrite Cu (In,Ga) (Se,S) 2 (CIGS) solar cell has been considered one of the most promising alternatives to conventional silicon solar cells, due to its achieving the highest power conversion efficiency (PCE) among all the thin-film photovoltaic technologies, potentially lowered production cost and compatibility with lar...
A review of primary technologies of thin-film solar cells
Thin-film solar cells are cheaper than mature c-Si wafer cells (sheets). Moreover, thin films are easier to handle and more flexible. They are also less vulnerable to destruction than their Si competitors. Although thin-film …
Beyond 30% Conversion Efficiency in Silicon Solar Cells: A
We demonstrate through precise numerical simulations the possibility of flexible, thin-film solar cells, consisting of crystalline silicon, to achieve power conversion efficiency of 31%. Our ...
High efficiency thin-film amorphous silicon solar cells
Enhancing light absorption within thin film amorphous silicon (a-Si) solar cells should lead to higher efficiency. This improvement is typically done using various light trapping techniques such as utilizing textured back …
High efficiency solution-processed thin-film Cu (In,Ga) …
The polycrystalline chalcopyrite Cu (In,Ga) (Se,S) 2 (CIGS) solar cell has been considered one of the most promising alternatives to conventional silicon solar cells, due to its achieving the highest power …
A review of thin film solar cell technologies and challenges
Thin film solar cells are favorable because of their minimum material usage and rising efficiencies. The three major thin film solar cell technologies include amorphous silicon (α-Si), copper indium gallium selenide (CIGS), and cadmium telluride (CdTe). In this paper, the evolution of each technology is discussed in both laboratory and ...
Self‐Regulated Growth of Large‐Grain Sb2S3 Thin Films for High ...
Self-Regulated Growth of Large-Grain Sb 2 S 3 Thin Films for High-Efficiency Solar Cells. Shihang Chen, Shihang Chen. Hubei Key Laboratory of Plasma Chemistry and Advanced Materials, School of Materials Science and Engineering, Wuhan Institute of Technology, Wuhan, 430205 P. R. China . Search for more papers by this author. Xiaomin …
Design and simulation of highly efficient CZTS/CZTSSe based thin-film …
Thin-film materials comprise direct bandgap and can absorb sunlight more efficiently than silicon. In this article, a double-absorber-based thin-film solar cell comprising CZTS/CZTSSe is designed and optimized through numerical simulation.
Cadmium‐Free Kesterite Thin‐Film Solar Cells with High …
In this work, we fabricated Ag-CZTSSe thin-film solar cells using eco-friendly ZTO as a buffer layer deposited by ALD method with optimal stoichiometry and film thickness, which significantly improved the efficiency of kesterite solar cells. …
Design and simulation of highly efficient CZTS/CZTSSe …
Thin-film materials comprise direct bandgap and can absorb sunlight more efficiently than silicon. In this article, a double-absorber-based thin-film solar cell comprising CZTS/CZTSSe is designed and optimized through …
Cadmium‐Free Kesterite Thin‐Film Solar Cells with High Efficiency ...
In this work, we fabricated Ag-CZTSSe thin-film solar cells using eco-friendly ZTO as a buffer layer deposited by ALD method with optimal stoichiometry and film thickness, which significantly improved the efficiency of kesterite solar cells. The experimental analysis confirms that the best PCE can be achieved with a 10 nm thick ZTO layer and ...
Photovoltaic solar cell technologies: analysing the state of the art ...
Kim, H.-S. et al. Lead iodide perovskite sensitized all-solid-state submicron thin film mesoscopic solar cell with efficiency exceeding 9%. Sci. Rep. 2, 591 (2012).
High-efficiency polycrystalline CdTe thin-film solar cells
Cadmium telluride (CdTe) has been recognized as a very promising material for thin-film solar cells. CdTe is a II–VI compound semiconductor with a direct optical bandgap of ∼1.5 eV that is nearly optimally matched to the solar …